Transition Metals Nanoparticles in Organic Synthesis (DOI: (10.2436/20.2003.01.23)

Authors

  • Miguel Yus Departamento de Química Orgánica, Facultad de Ciencias e Instituto de Síntesis Orgánica (ISO), Universidad de Alicante

Keywords:

nanoparticles, reduction, C-C bond formation, click chemistry, copper, nickel, iron.

Abstract

The reduction of nickel chloride (II) dihydrate with lithium and a catalytic amount (5-10%) of naphthalene or DTBB leads to the formation of highly reactive metallic nickel nanoparticles, which have been used for the reduction of different functionalities (olefins, acetylenes, halogenated derivatives sulfonates, aromatic compounds, carbonyl derivatives and imines, and other aromatic compounds) and for reactions generating carbon-carbon bonds (homocouplings, ketone alkylations, and Wittig-type and aza-Wittig reactions). The same procedure was also applied to prepare nanoparticles of copper and iron, which have proved to be very active in reduction processes (dehalogenation, desulfonylation, and
reduction of carbonyl compounds and imines) and 'click'
chemistry.

Keywords: nanoparticles, reduction, C-C bond formation,
click chemistry, copper, nickel, iron.

Downloads

Download data is not yet available.

Author Biography

Miguel Yus, Departamento de Química Orgánica, Facultad de Ciencias e Instituto de Síntesis Orgánica (ISO), Universidad de Alicante

Miguel Yus nació en Zaragoza en 1947, en cuya Universidad estudió Química (1969) y realizó su Doctorado (1973). Después de dos años de posdoctorado en el Max Planck Institut de Mülheim (Alemania) volvió a la Universidad de Oviedo, donde fue Profesor Adjunto (1977) y Catedrático (1987). En 1988 se trasladó a la Universidad de Alicante como Catedrático de Química Orgánica, siendo en la actualidad Director del Instituto de Síntesis Orgánica. Es coautor de más de 500 publicaciones, ha impartido más de 150 conferencias y fundó la empresa MEDALCHEMY S. L. para comercializar productos de química fina.

Downloads

Issue

No. 10 (2011)

Section

Articles

License

The intellectual property of articles belongs to the respective authors.

On submitting articles for publication to the journal Revista de la Societat Catalana de Química, authors accept the following terms:

  1. Authors assign to Catalan Society of Chemistry (a subsidiary of Institut d’Estudis Catalans) the rights of reproduction, communication to the public and distribution of the articles submitted for publication to Revista de la Societat Catalana de Química.
  2. Authors answer to Catalan Society of Chemistry for the authorship and originality of submitted articles.
  3. Authors are responsible for obtaining permission for the reproduction of all graphic material included in articles.
  4. Catalan Society of Chemistry declines all liability for the possible infringement of intellectual property rights by authors.
  5. The contents published in the journal, unless otherwise stated in the text or in the graphic material, are subject to a Creative Commons Attribution-NonCommercial-NoDerivs (by-nc-nd) 3.0 Spain licence, the complete text of which may be found at  http://creativecommons.org/licenses/by-nc-nd/3.0/es/deed.en. Consequently, the general public is authorised to reproduce, distribute and communicate the work, provided that its authorship and the body publishing it are acknowledged, and that no commercial use and no derivative works are made of it.
  6. The journal is not responsible for the ideas and opinions expressed by the authors of the published articles.