C60 functionalization-oriented synthesis based on transition metal-catalyzed enyne cyclizations Authors Pau Godori Anna Pla-Quintana Anna Roglans DOI: 10.2436/20.2003.01.155 Keywords: Cyclizations, transition metal catalysis, 1,6-enynes, fullerene, rhodium, ruthenium. Abstract In recent decades, the functionalization of fullerenes has become a topic of interest in the scientific community due to the significant applications of these compounds in such research fields as biomedicine, materials science, and photovoltaic cells development. When fullerenes are functionalized, their properties can be modified, making it possible to expand their applicability in these different areas. This study presents a method for functionalizing C60 through cyclization reactions with 1,6-enynes catalyzed by transition metals such as rhodium and ruthenium. By employing different rhodium and ruthenium catalytic systems and optimizing the reaction conditions, a diversified synthesis of functionalized fullerenes is achieved from the same starting substrates. Downloads Download data is not yet available. Downloads PDF (Català) Issue No. 23 (2024) Section Articles License The intellectual property of articles belongs to the respective authors. On submitting articles for publication to the journal Revista de la Societat Catalana de Química, authors accept the following terms:Authors assign to Catalan Society of Chemistry (a subsidiary of Institut d’Estudis Catalans) the rights of reproduction, communication to the public and distribution of the articles submitted for publication to Revista de la Societat Catalana de Química.Authors answer to Catalan Society of Chemistry for the authorship and originality of submitted articles.Authors are responsible for obtaining permission for the reproduction of all graphic material included in articles.Catalan Society of Chemistry declines all liability for the possible infringement of intellectual property rights by authors.The contents published in the journal, unless otherwise stated in the text or in the graphic material, are subject to a Creative Commons Attribution-NonCommercial-NoDerivs (by-nc-nd) 3.0 Spain licence, the complete text of which may be found at http://creativecommons.org/licenses/by-nc-nd/3.0/es/deed.en. Consequently, the general public is authorised to reproduce, distribute and communicate the work, provided that its authorship and the body publishing it are acknowledged, and that no commercial use and no derivative works are made of it.The journal is not responsible for the ideas and opinions expressed by the authors of the published articles.
