Synthesis and applications in catalysis of P-stereogenic ligands: SIP, MaxPHOS, MaxPHOX

Authors

  • Ernest Salomó Institut de Recerca Biomèdica (IRB) de Barcelona
  • Antoni Riera Institut de Recerca Biomèdica (IRB) de Barcelona
  • Xavier Verdaguer Institut de Recerca Biomèdica (IRB) de Barcelona

Keywords:

Catalysts, ligands, P-stereogenic, hydrogenations, SIP, MaxPHOS, MaxPHOX.

Abstract

Catalysis is an important tool for organic synthesis. Despite frequent breakthroughs, there is still a need for new ligands and catalysts. Among the numerous ligands, phosphine-type ligands stand out. And within these are the ligands bearing chirality on phosphorus, which have great potential but are challenging to synthesise. In our group we have developed an efficient synthesis for different chiral phosphorous synthons and from these, we designed several ligands (SIP, MaxPHOS, MaxPHOX). Coordination to different metals has given rise to catalysts that afford excellent results in catalytic reactions such as cycloadditions or asymmetric hydrogenations.

Keywords: Catalysts, ligands, P-stereogenic, hydrogenations, SIP, MaxPHOS, MaxPHOX.

Downloads

Download data is not yet available.

Downloads

Issue

No. 15 (2016)

Section

Articles

License

The intellectual property of articles belongs to the respective authors.

On submitting articles for publication to the journal Revista de la Societat Catalana de Química, authors accept the following terms:

  1. Authors assign to Catalan Society of Chemistry (a subsidiary of Institut d’Estudis Catalans) the rights of reproduction, communication to the public and distribution of the articles submitted for publication to Revista de la Societat Catalana de Química.
  2. Authors answer to Catalan Society of Chemistry for the authorship and originality of submitted articles.
  3. Authors are responsible for obtaining permission for the reproduction of all graphic material included in articles.
  4. Catalan Society of Chemistry declines all liability for the possible infringement of intellectual property rights by authors.
  5. The contents published in the journal, unless otherwise stated in the text or in the graphic material, are subject to a Creative Commons Attribution-NonCommercial-NoDerivs (by-nc-nd) 3.0 Spain licence, the complete text of which may be found at  http://creativecommons.org/licenses/by-nc-nd/3.0/es/deed.en. Consequently, the general public is authorised to reproduce, distribute and communicate the work, provided that its authorship and the body publishing it are acknowledged, and that no commercial use and no derivative works are made of it.
  6. The journal is not responsible for the ideas and opinions expressed by the authors of the published articles.