The Principles of Gold-Catalyzed Molecular Gymnastics

Autores/as

  • Patricia Pérez-Galán Institute of Chemical Research of Catalonia (ICIQ), Tarragona
  • Verónica López-Carrillo Institute of Chemical Research of Catalonia (ICIQ), Tarragona
  • Antonio M. Echavarren Institute of Chemical Research of Catalonia (ICIQ), Tarragona

Resumen

Gold(I) orchestrates molecular gymnastics by intra and intermolecular reaction of enymes via highly distorted cyclopropyl gold carbenes as intermediates. The synthesis of natural products such as (+)-orientalol F and (-)-englerin A illustrates the state of the art of gold (I) catalysis for the buildup
of molecular complexity.

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