Applications of optically active metallacycles: new useful materials for the determination of the enantiomeric excess of Lewis bases and as resolvin agents for monodentate phosphines Authors Guillermo Muller Jaume Ramon Granell Abstract The synthesis of new optically active cyclopalladated derivatives containing imines and primary amines is described as well as their applications for the determination of the enantiomeric excess and as resolving agents of Lewis bases. The synthesis and resolution of new monodentate P-chiral tertiary phosphines is also reported, as well as the application of these new ligands to asymmetric catalysis. Besides this, some chiral secondary phosphines have been prepared and their configurational stability has been studied. Downloads Text complet Published 2003-07-29 Issue 2-1 Section Research reviews License This work is subject, unless the contrary is indicated in the text, the photographs or in other illustrations, to an Attribution —Non-Commercial— No Derivative Works 3.0 Creative Commons License, the full text of which can be consulted at http://creativecommons.org/licenses/by-nc-nd/3.0/. You are free to share, copy, distribute and transmit the work provided that the author is credited and reuse of the material is restricted to non-commercial purposes only and that no derivative works are created from the original material.
